This is a solution reaction that you may well only meet in the context of catalysis, but it is a lovely example! Iodine can easily be oxidized, and the peroxodisulfate ion can easily act as an oxidizing agent.
Persulphate ions (peroxodisulphate ions), S 2 O 8 2-, are very powerful oxidising agents. One of the earliest and most efficient catalysts for effecting this transformation is Wilkinson's catalyst, chlorotris-(triphenylphosphine) rhodium, [(Ph 3 P) 3 RhCl]. An example of a homogeneous catalyst is oxidizing iodide ions with peroxodisulfate ions.
With this system, hydrogen addition occurs in a syn fashion, and isomerization is less prevalent.
Iodide ions are very easily oxidised to iodine. Homogeneous catalysis is a powerful tool for the hydrogenation of olefins.
Examples of homogeneous catalysis. An advantage of homogeneous catalysis is that the catalyst mixes into the reaction mixture, allowing a very high degree of interaction between catalyst and reactant molecules.
The reaction between persulphate ions and iodide ions. The reaction between persulphate ions and iodide ions This is a solution reaction that you may well only meet in the context of catalysis, but it is a lovely example! Examples of homogeneous catalysis. Homogeneous catalysis: The catalyst is in the same phase as the reactants The reaction between ethanol and ethanoic acid is very slow even when heat is applied. Iodide ions are very easily oxidised to iodine. Persulphate ions (peroxodisulphate ions), S 2 O 8 2-, are very powerful oxidising agents. However, unlike with heterogeneous catalysis, the homogeneous catalyst is often …
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